To determine the presence of anion and cation in the given salt
Experiment | Observation | Inference |
---|---|---|
Salt + Conc H₂SO₄ | Colorless gas evolves that etches glass | F⁻ may be present |
Confirmatory Test | ||
Calcium Chloride Test Salt Solution + CaCl₂ solution | White gelatinous ppt forms | Presence of F⁻ anion is confirmed |
Experiment | Observation | Inference |
---|---|---|
Salt + NaOH solution | No reaction | Zero group cation is absent |
Original salt + Dil. HCl | No reaction | First group cation is absent |
Original salt + Dil. HCl + H₂S gas (Na₂S chips) | No reaction | Second group cation is absent |
Original salt + Dil. HCl + NH₄Cl solid + NH₄OH solution | No reaction | Third group cation is absent |
Original solution + Dil. HCl + NH₄Cl + NH₄OH + (NH₄)₂CO₃ | White ppt is formed | Ba²⁺ may be present |
Confirmatory Tests | ||
Dissolve the white ppt in dil. acetic acid and add potassium chromate | No reaction | Ba²⁺ absent |
Dissolve the white ppt in dil. acetic acid and add (NH₄)₂SO₄ | White ppt | Sr²⁺ confirmed |
The given salt contains Sr²⁺ ions as cation and F⁻ ions as anion. The salt is Sr²⁺F⁻.