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Experiment No. N

Analysis of Nickel(II) Oxalate (NiC₂O₄)

Aim

To determine the presence of anion and cation in the given salt

Preliminary Test

  • Odor: Odorless
  • Texture: Crystalline
  • Color: White
  • Solubility: Slightly soluble in water

Test of Anion

ExperimentObservationInference
Take 0.1 g salt and add conc. H₂SO₄Colourless gases are evolved. On testing further, CO₂ and CO are evolvedC₂O₄²⁻ may be present
Confirmatory Tests
Calcium Chloride Test
Acidify extract with acetic acid and add calcium chloride		White precipitate of calcium oxalate is obtainedC₂O₄²⁻ is confirmed
KMnO₄ Test
Filter and add dilute H₂SO₄ to the precipitate, then dilute KMnO₄ and warm		KMnO₄ pink colour is dischargedC₂O₄²⁻ is confirmed

Test of Cation

ExperimentObservationInference
Original solution + H₂S gas in presence of NH₄OHBlack precipitate is formedGroup IV cation may be present
Dissolve black precipitate in aqua regiaNickel chloride solution is obtainedNi²⁺ may be present
Confirmatory Test
Dimethylglyoxime Test
Make the solution alkaline with NH₄OH and add dimethylglyoxime		Brilliant red precipitatePresence of Ni²⁺ is confirmed

Result

The given salt contains Ni²⁺ ions as cation and C₂O₄²⁻ ions as anion. The salt is NiC₂O₄.

Precautions

  1. Handle the chemicals with care.
  2. Don't use excess of chemicals.
  3. Keep the mouth of the test tube away from the face.