Notebook Theme

Experiment No. N

Analysis of Manganese(II) Phosphate ((Mn)₃(PO₄)₂)

Aim

To determine the presence of anion and cation in the given salt

Preliminary Test

  • Odor: Odorless
  • Texture: Crystalline
  • Color: White
  • Solubility: Slightly soluble in water

Test of Anion

ExperimentObservationInference
Confirmatory Test
Ammonium Molybdate Test
Acidify with conc. HNO₃ and add ammonium molybdate solution, boil
Canary yellow precipitate is formedPO₄³⁻ is confirmed

Test of Cation

ExperimentObservationInference
Original solution + H₂S gas in presence of NH₄OHBlack or flesh-coloured precipitate is formedGroup IV cation may be present
Confirmatory Test
Sodium Hydroxide Test
Dissolve the precipitate in dilute HCl by boiling and add NaOH in excess
White precipitate forms first, then turns brown on standingPresence of Mn²⁺ is confirmed

Result

The given salt contains Mn²⁺ ions as cation and PO₄³⁻ ions as anion. The salt is (Mn)₃(PO₄)₂.

Precautions

  1. Handle the chemicals with care.
  2. Don't use excess of chemicals.
  3. Keep the mouth of the test tube away from the face.