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Analysis of Magnesium Hydroxide (Mg(OH)₂)

Qualitative analysis

Aim

To analyse the given inorganic salt for one acidic and one basic radical.

Preliminary Test

  • Colour: White
  • Odour: Odourless
  • State: Crystalline solid
  • Solubility: Insoluble in water

Test of Anion (OH⁻)

ExperimentObservationInference
Universal IndicatorSolution turns blue or purpleOH⁻ may be present
Confirmatory Test
Phenolphthalein Test
Add phenolphthalein indicator to salt solution
Solution turns pinkOH⁻ is confirmed

Test of Cation (Mg²⁺)

ExperimentObservationInference
Confirmatory Tests
If Group V is absent, add disodium hydrogen phosphate solution and scratch the inner walls with a glass rodA white crystalline precipitate of magnesium ammonium phosphate is formedMg²⁺ may be present
Magneson Test
To the alkaline solution add a drop of Magneson I reagent (p-nitrobenzeneazoresorcinol)
A blue precipitate / blue lake is formedMg²⁺ is confirmed

Result

The given salt contains Mg²⁺ as the cation (basic radical) and OH⁻ as the anion (acidic radical). The salt is Magnesium Hydroxide (Mg(OH)₂).

Precautions

  1. Handle the chemicals with care.
  2. Don't use excess of chemicals.
  3. Keep the mouth of the test tube away from the face.