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Analysis of Potassium Hydroxide (KOH)

Qualitative analysis

Aim

To analyse the given inorganic salt for one acidic and one basic radical.

Preliminary Test

  • Colour: White
  • Odour: Odourless
  • State: Crystalline solid
  • Solubility: Soluble in water

Test of Anion (OH⁻)

ExperimentObservationInference
Universal IndicatorSolution turns blue or purpleOH⁻ may be present
Confirmatory Test
Phenolphthalein Test
Add phenolphthalein indicator to salt solution
Solution turns pinkOH⁻ is confirmed

Test of Cation (K⁺)

ExperimentObservationInference
Flame test in a clean non-luminous flameLilac flameK⁺ may be present
Confirmatory Test
Sodium Cobaltinitrite Test
Salt solution + sodium cobaltinitrite reagent
Yellow precipitateK⁺ is confirmed

Result

The given salt contains K⁺ as the cation (basic radical) and OH⁻ as the anion (acidic radical). The salt is Potassium Hydroxide (KOH).

Precautions

  1. Handle the chemicals with care.
  2. Don't use excess of chemicals.
  3. Keep the mouth of the test tube away from the face.