To determine the presence of anion and cation in the given salt
| Experiment | Observation | Inference |
|---|---|---|
| Take 0.1 g of salt in a test tube and add conc. H₂SO₄ (or add MnO₂ if needed) and warm | Reddish brown fumes of bromine are evolved | Br⁻ may be present |
| Confirmatory Tests | ||
| Layer Test Take 1 mL of neutralized extract, add CCl₄/CHCl₃ (or other suitable organic solvent), then add chlorine water dropwise and shake vigorously | Orange-brown colouration appears in the organic layer | Br⁻ is confirmed |
| Silver Nitrate Test Acidify sodium carbonate extract with dilute HNO₃ (or use water extract) and add AgNO₃ | Pale yellow precipitate | Br⁻ is confirmed |
| Experiment | Observation | Inference |
|---|---|---|
| Salt solution + NaOH solution | Dirty green precipitate | Fe²⁺ may be present |
| Confirmatory Test | ||
| Potassium Ferricyanide Test Add potassium ferricyanide solution | Dark blue precipitate (Turnbull's blue) | Presence of Fe²⁺ is confirmed |
The given salt contains Fe²⁺ ions as cation and Br⁻ ions as anion. The salt is Fe(Br)₂.