To determine the presence of anion and cation in the given salt
| Experiment | Observation | Inference |
|---|---|---|
| Take 0.1 g of salt in a test tube and add conc. H₂SO₄ (or add MnO₂ if needed) and warm | Reddish brown fumes of bromine are evolved | Br⁻ may be present |
| Confirmatory Tests | ||
| Layer Test Take 1 mL of neutralized extract, add CCl₄/CHCl₃ (or other suitable organic solvent), then add chlorine water dropwise and shake vigorously | Orange-brown colouration appears in the organic layer | Br⁻ is confirmed |
| Silver Nitrate Test Acidify sodium carbonate extract with dilute HNO₃ (or use water extract) and add AgNO₃ | Pale yellow precipitate | Br⁻ is confirmed |
| Experiment | Observation | Inference |
|---|---|---|
| Original solution + Dil. HCl + NH₄Cl solid + NH₄OH | White gelatinous precipitate | Al³⁺ may be present |
| Confirmatory Tests | ||
| Dissolve white precipitate in dilute HCl and divide into two parts | To the first part, add sodium hydroxide and warm. A white gelatinous precipitate dissolves in excess sodium hydroxide solution | Aluminium is confirmed |
| Blue Lake Test To the second part, add few drops of blue litmus solution and then NH₄OH dropwise along the sides of the test tube | A blue floating mass appears in colourless solution | Presence of Al³⁺ is confirmed |
The given salt contains Al³⁺ ions as cation and Br⁻ ions as anion. The salt is Al(Br)₃.